In article questions of pilot studies of disperse structure of drop ablation are considered when putting electroplated coatings, the technique of performance of experiment is given, the design of experimental installation is considered, results of researches of dependence of height of take-off of drops of ablation over an electrolyte surface from their effective radius are given
Keywords: electroplated coatings, drop ablation, bubbling, drop, height of take-off of a drop, effective radius of a drop
We study the problems in the propagation of acoustic waves of a sound range near the boundaries of media. The features of the wave processes occurring at the water-air interface, due to the influence of inhomogeneous waves. Considered in detail the properties and parameters of an inhomogeneous plane wave. The mathematical calculations of the transmission coefficients L.M. Brekhovskikh for spherical and cylindrical waves through this boundary, allowing to take into account the contribution of inhomogeneous components. It is shown that than the frequency of radiation of a source is lower and the closer it is located to water-air interface, the acoustic transparency of this border is higher. Study of the dependence of the transmission coefficient of the water-air interface at low frequencies can have important consequences in a number of fundamental and applied problems. Increase the transparency of the interface requires a reassessment of the feasibility of acoustic communication from water in the air, the detection of underwater sources without dipping into the water and acoustic monitoring of the physical processes occurring in the water.
Keywords: Inhomogeneous plane wave, water-air interface, transmission coefficient, wavelength, spherical wave, acoustic impedance.
"This review covers various methods of synthesis LaMnO3 ferroics. The general analysis of the solid-phase synthesis reactions methods and wet methods (sol-gel, sorption, co-precipitation) are carred out. The original results of LaMnO3 syntheses from various precursors by means of the in situ method are showned. The advantages and disadvantages of different methods of synthesis are determined. The analysis of synthesis LaMnO3 ferroics published data is shown:
- the structure formation of LaMnO3 in perovskite-type phases occurs at different temperatures, depending on precursors states;
- LaMnO3 perovskite phases differ in symmetry and unit cells parameters at room temperature, depending on the preparation conditions;
- the highest synthesis temperature of LaMnO3 are typical for solid phase reactions method (950-1050 ° C), the lowest - for wet synthesis methods (500-700 ° C);
- the synthesis conditions effect the stoichiometry of LaMnO3 for oxygen content.
Our studies of structure formation processes of LaMnO3 by in situ method are allowed to define the role of precursors states at synthesis of solid phase reactions methods, adsorption, co-precipitation and sol-gel mixtures.
It is determined that in samples prepared by wet chemical methods, the formation processes of LaMnO3 perovskite phases occur at lower temperatures than by solid phase reaction (sol-gel precursor - 500 <T <600 ° C; precursors obtained by coprecipitation and sorption methods - at 600 <T <700 ° C and 700 <T <800 ° C, respectively).
Keywords: ferroics, LaMnO3, X-ray diffraction, solid-phase synthesis, sol-gel synthesis, sorption, co-precipitation
The existing methods of calculation of the annual change in soil temperature. Identified areas of their application and the possible deviations from reality. The requirements to the boundary conditions of the calculation. Defines the principles of the choice of initial conditions. The preconditions for the development of a universal method of calculation.
Keywords: heat pump, renewable energy, solar radiation, transient mode, soil
In article negative impact of objects of municipal economy on an urban environment, on the example of a site of charging of accumulators of the motor transportation enterprise is considered. The physical model of process of pollution of the air environment is developed for a site of charging of accumulators on ATP. The description is given to basic elements of model (technological raw materials, processing equipment, etc.), participating in air pollution process.
Keywords: the municipal economy polluting substance, process of pollution of the air environment, technological raw materials, processing equipment
Considers the most important sources of material pollution of urban territories. A comprehensive approach to studying properties of pollutants, based on the theory of disperse systems. Built block diagram of systematization of parameters that determine the behavior of contaminants from the position of theory of disperse systems. The dependence between the behavior of pollutant aerosol and parameters of its stability.
Keywords: Contaminant dispersion system, the parameters of pollutant properties, stability of pollutant aerosol
Considered relevant for the construction industry the problem of air pollution by dust. A significant level of airborne dust is typical for plants of concrete products and structures. A physical model of the process of mixing of air pollution department, which includes the main stage of the contamination: education, allocation and distribution of pollutants. Ustanovnleno that the main objects of the physical model are contaminant technological raw materials, manufacturing equipment, the workplace air and the ground layer of the atmosphere.
Keywords: Contaminant technological raw materials, manufacturing equipment, workplace air, the physical model of air pollution
The establishment of automated air monitoring systems is a promising way of the air monitoring devices development. The comparative analysis of literature has shown that thin films based on semiconductor metal oxides are effective and widely used material for air monitoring systems creation. In order to create effective and more sensitive sensors it is important to research processes that occur on the surface of the gas sensitive material when it contacts with different substances. The processes that proceed on the surface of gas sensitive material based on SiO2SnOxCuOy during the interaction with molecules of nitrogen dioxide. Quantum chemical calculations have shown that there are three possible mechanisms of interaction between the molecules of nitrogen dioxide with a surface of gas sensitive material.
Keywords: multitouch system of the monitoring, gas-sensitive material, molecules of dioxide of nitrogen
The problem of air quality control is relevant at the present time. There are a lot of different devices and methods of air monitoring. The promising devices for air monitoring are automated air monitoring systems functioning in real time regime. The basic part of such system is a chemical gas sensor. Gas sensors can be combined into the arrays or so called multisensory systems to increase their effectiveness. Sensor arrays using semiconductor sensors based on SiO2CuOx, SiO2SnOxCuOy, SnOxZrOy, silver-polyacrylonitrile thin films made at department of chemistry and ecology have been investigated in this work. As a result of sensors signals processing gas recognition technique has been developed. The recognition of ammonia, nitrogen dioxide, chlorine has been made.
Keywords: monitoring, massifs of sensors, semiconductor sensors of gases
We have investigated electrical and gas sensitive properties of gas sensor based on carbon nanotubes (CNT) and carbon nanotubes modified by metal oxides (such as tin oxide and silicon oxide). Also we have find out that modification of CNT by metal oxides helps to improve film`s adhesion to substrate, decrease electrical resistance, recovery time, working temperature , enhance gas sensitivity in comparison with sensitive elements based only on CNT or metal oxides. Moreover experimental results showed that properties of composite material depend on concentration correlation of solutions. As a result we can get highest sensitivity of sensor element by choosing optimal relation between concentrations of solutions.
Keywords: Сarbon nanotubes, modification, tin oxide, silicon oxide, gas sensor
Neural network model of distribution of pollutant in the atmosphere of the city of Taganrog has been developed on the basis of monitoring data, meteorological information and calculation made by software «Ecolog-gorod». The results of the work of model have been visualized in software ArcGis. Distribution maps of nitrogen dioxide has been built under the conditions of eight directions of wind, two wind speeds and two temperature ranges.
Keywords: Neural network, prediction model, urban air pollution
Results of research the ties of refrectory oxide, which form in the course of filling with stainless steels, and specific point defects impairing casts of stainless steel.
Keywords: quartz mould, chromium steel, oxides, chemical analysis, physicochemical interaction
In article are considered questions of the study of the composition of the drip of ash from galvanic bath with the application of chromium coatings, the results of research concentrations of chromium above the surface of the bath and in the working zone depending on the height above the mirror electrolyte
Keywords: working zone, galvanic bath, drip ash, chrome, local capturing
It is considered the dependence of the operation mode of floor radiant panel heating systems depending on the design parameters for the internal air
Keywords: panel-radiant heating, heat-insulated floor, parameters of the internal air
The state of the atmospheric air in such industrial cities of the Rostov region, as Belaya Kalitva, Donetsk, Kamensk-Shakhtinsky over the last 10 years (2003-2012). Identified main pollution sources and priority pollutants. Analysis of the concentrations of pollutants in areas of concentration of industrial enterprises, on highways and in dwelling zones. It is established that industrial cities are specific «geochemical provinces», in which abnormally elevated concentrations of many chemical elements. On the background of the decrease of the role of industrial enterprises in the air pollution increases the role of motor transport
Keywords: Anthropogenous influence, industrial production, ecological situation, environment, an ecosystem, the industry, transport, pollution.