We have carried out the analysis on the scientific and technological literature on methods of calculation and analysis of the x-ray diffraction, x-ray absorption and Raman spectra used to analyse the structure of the materials for hydrogen storage under realistic operating conditions. The simulations were carried out for the series of small palladium nanoclusters with embedded hydrogen. Multiscale computer modelling was used to simulate the dynamics of structure of the materials during charge/discharge phases.
Keywords: hydrogen storage, XANES, x-ray diffraction, Raman scattering, fuel cell
The article presents the results of experimental research of the re-entrainment reduction in the electrocyclone. The authors shows an increase in the collection efficiency of ash up to 99.5% and reduction of entrainment in 4 times when profiled elements was install on collection electrode surface
Keywords: gas dust cleaning, electrocyclone, re-entrainment, collection efficiency, ash from thermal power plants
The proposed approach to the study of social engineering systems to meet all their basic features. Blurred structure of social engineering system reflects the fuzzy cognitive model; Fuzzy connection effectively evaluated using weights Fishburne; "blur" element values system and its functioning is overcome by introducing linguistic variables and their term-set fuzzy classifiers.
Keywords: system analysis, poorly structured and poorly formalizable processes, sociotechnical systems, fuzzy cognitive modeling
Examines the historical stages in the development of the theory of systems research management of the uncertainties, the reasons for they arise in the mathematical model, this is reflected in an interval values in the transfer function of the object of control. It is proposed algorithm for obtaining experimentally the interval of values.
Keywords: interval values, robust stability, the transfer function, parametric uncertainty, a mathematical model of the management system
The mathematical model of storage reservoir has been deduced. The deposition rate of particles in reservoir has been calculated. It is concluded that storage reservoir is a preliminary sedimentation tank.
Keywords: storage reservoir, preliminary sedimentation tank, mathematical model, deposition rate
In article questions of improvement of a technique and theoretical bases of electrocatching with reference to problems of fight against drop ablation in a working zone in the conditions of galvanic production are considered.
Keywords: electrocatching, drop ablation, working zone, barbotage, charge, drop
When introducing a new facility to improve the transport network, there are appear many risks. The priority is the financial riskbecause core funding for these projects comes from private organizations. Careful calculation of demand is an integral part of the development project. For the effective analysis of the transport network since the project requires a conscientious approach to the latest technology.
Keywords: Transport network: improving objects, Transport network, Demand for transport routes, Traffic flow, Mathematical modeling of demand
It is proposed software-technological complex for modeling, which uses L-systems (Lindenmayer Systems) as the tools of modeling and visualization. The main purpose is to construct models of processes and structures that have a fractal nature. The complex supports different types of L-systems: deterministic context-free L-systems, stochastic L-systems, parametric L-systems, context sensitive L-systems. The developed tools have been used to model and analyze the socio-economic processes.
Keywords: L-systems, modeling, Fractal, Self-similar structures, Production rules, Grammar, Graphic interpretation
In article the technique of optimization of placement of waste reloading stations, allowing to define both location, and number of stations that allows to reduce both operational and capital expenditure for the organization and functioning of system of the address with a waste is offered.
Keywords: technological process of transportation, a solid municipal waste, critical distance
The article describes methods allows to control the degree of anisotropy piezoelectric ceramics based on doped phase PbTiO3. As a model of the object has been selected phase of Pb0,76Ca0,24Ti0,94(Cd0,5W0,5)0,06O3. The model phase was obtained by the following methods: by solid state reaction method and the chemical construction. For comparison phases obtained by these methods were used modern analytical research methods (DTA, TGA, XRF, XRD, power and tunneling microscopy, computer-program research results). Piezoceramic samples were obtained from the synthesized phases and electrical parameters were measured. Were revealed that the samples, obtained from the charge, synthesized by chemical construction had values of piezoelectric constants d31 and d33 much more than samples obtained by the method of solid state reaction.
Keywords: piezoelectric ceramics, anisotropy, ultrasonic issue systems.
Keywords: piezoelectric ceramics, anisotropy, ultrasonic issue systems
Theoretical model of anomalous electron emission has built for an soft x-ray irradiation of surface elektrets, explaining the different character of correlation between energy and emission intensity of ferroelectric solid solution PbTiO3 - CaTiO3 and nonferroelectric ceramics CaTiO3. Shown that due electret surface irradiation the Schottky area is depleted by nonequilibrium charge carriers.
Keywords: Emission, electret, ferroelectricity, Schottky area
Investigated the quality of the surface layer of weld metal cylindrical part in the combined processes of under the flux layer welding and cutting, as well as follow grinding of weld metal in the hot and cold. Showing photos of the weld surface and the machined part and its structure
Keywords: grinding, hot weld metal, structure of the metal, micro hardness.
The system organization assumes formation of the scientific construction complex providing builder’s competitiveness. Sated network model sare perspective.
Keywords: System organization, information, model, investments, market, management
It is shown that to describe the phenomena and processes in a transition interfacial layer having a certain thickness, it is useful to distinguish the boundary layer of the surface and boundary diffusion layer, which lies entirely in the less condensed phase related. In accordance with this energy and power characteristics of the transition layer should be attributed to the boundary surface of the interphase transition layer. The basic equation of electro capillary boundary of the surface layer, establishing the dependence of the surface tension of this layer on the chemical composition of the second phase, and bordering the jump of electric potential between them.
Keywords: Interphase layer, Entropy, Concentration, Adsorption, Surface tension boundary layer, the surface energy, electrochemical electrode
Analog-to-digital converter, with modulation, amplification and demodulation of the input signal is carried out. To compensate the additional error of voltage conversion, concerned with temperature instability, used dynamic cancellation technique, based on the correlation between offset voltage and modulator temperature fluctuation. ADC with response time 0.85 s performs the threshold of sensitivity 1 nV; 8,5 s - 0,31 nV, 85 s - 0.13 nV, 850 s - 0.1 nV, respectively, in the full-scale range 400 mV. Estimation of offset voltage temperature drift is 40 pV / ºC, time drift - 100 pV / h.
Keywords: analog-to-digital converter, ADC, error cancellation.